Despite the intricate dynamic nature of emotional states, there are very few public datasets that measure people’s emotions seamlessly over time. To fill this gap, the MobileWell system was used in this research to collect a novel open dataset. Over one hundred adults were selected to form a representative sample of the Spanish population, balanced in terms of gender, age, location, and annual income. Participants installed the MobileWell app and kept it on their phones for one month, during which they received digital questionnaires several times a day. These questionnaires collected self-reported data related to health status, emotions, and well-being, providing a comprehensive view of the participants’ social, behavioural, emotional, and well-being states. Specifically, this research focused on the assumption that emotional states can be either positive (joy, satisfaction, pleasure) or negative (sadness, frustration, anxiety). Hence, participants were asked six times a day to rate how they felt on a scale from very bad to very good. In terms of psychological well-being, participants were asked to report on several indicators. The Flourishing Scale was used to measure self-perceived success, while the Brief Resilience Scale captured the ability to recover from stress. The Satisfaction with Life Scale assessed perceived life satisfaction. The Generalized Anxiety Disorder Scale measured anxiety-related symptoms, and the Patient Health Questionnaire-9 evaluated the frequency of various prominent depression symptoms. Finally, the Acceptance and Action Questionnaire-II measured the level of experiential avoidance. This comprehensive approach provides a detailed understanding of the participants’ emotional and psychological well-being.